ANACHEMIA -- SULFURIC ACID SOLUTIONS -- 6810-01-347-9118
===================== Product Identification ===================== Product ID:SULFURIC ACID SOLUTIONS MSDS Date:09/21/1989 FSC:6810 NIIN:01-347-9118 === Responsible Party === Company Name:ANACHEMIA Address:3 LINCOLN BLVD City:ROUSES POINT State:NY ZIP:12979 Country:US Info Phone Num:518-297-4444 Emergency Phone Num:518-297-4444;800-424-9300(CHEMTREC) Preparer's Name:A. SEYMOUR CAGE:HO801 === Contractor Identification === Company Name:ANACHEMIA Address:3 LINCOLN BLVD Box:City:ROUSES POINT State:NY ZIP:12979 Country:US Phone:518-297-4444 CAGE:HO801 Company Name:ANACHEMIA CHEMICALS INC Address:3 LINCOLN BLVD Box:City:ROUSES POINT State:NY ZIP:12979 Country:US Phone:518-297-4444 CAGE:4A444 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 0.3-40% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3;3 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 2140 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: CORROSIVE, OXIDIZING AND SULFONATING PROPERTIES ON CONTACT. EYES: VAPORS ARE IRRITATING AND CORROSIVE. CAUSES SEVERE BURNS. MAY CAUSE PERMANENT DAMAGE. CHRONIC EFFECTS. SKIN: CAUSES SEVERE BURN S. DEFAT DERM WITH PRLNGD USE. DESTRUCTIVE TO TISS. SYMP SIMILAR TO THERM BURNS. PAINT SHOCK, COLLAPSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: W/EXPOS OVER LRG AREAS. INHAL:INHAL OF VAPS CAUSES SEV IRRIT/BURNS OF RESP SYS, PULM EDEMA/LUNG INFLAM. RPTD/PRLNGD CONT MAY LEAD TO CHRONIC BRONCH. INGEST: BURNS IN MOUTH, PHARYNX AND GI TR ACT. NAUS, VOMIT. MAY HAVE ADVERSE EFTSON KIDNEY FUNCT. MAY CAUSE DEATH.CORR TO BODY TISS. EROSION OF TEETH. LUNG DMG. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: WASH WITH COPIOUS QTYS OF WATER FOR AT LEAST 15 MINUTES. CALL PHYS. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAM CLTHG. CALL PHYS. INHALATION: REMOVE PATIENT TO FRESH AIR. ADMIN APPROVED OXYGEN SUPPLY IF BREATHING IS DFCLT. ADMIN ARTF RESP OR CPR IF BREATHING HAS CEASED. CALL PHYS. INGEST: KEEP PATIENT WARM & QUIET. GIVE LRG QTY OF H*2O TO DILUTE. DO NOT INDUCE VOMITING. CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE. DRY CHEMICAL POWDER. DO NOT USE WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT . WEAR ADEQUATE PERSONAL PROT TO PREVENT CONT WITH MATL OR ITS COMBUST PRODS. Unusual Fire/Explosion Hazard:NOT FLAMMABLE BUT HIGHLY REACTIVE AND CAPABLE OF IGNITING FINELY DIVIDED COMBUSTIBLE MATLS ON CONTACT. REACTS VIOLENTLY W/H*2O AND ORGANICS W/EVOLUTION OF HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:COVER WITH SODA ASH OR LIME. SWEEP UP AND PLACE IN CONTAINER FOR DISPOSAL. WASH SPILLAGE SITE WITH SOAP AND WATER. WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. Neutralizing Agent:SODA ASH OR LIME. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN DIRECT SUNLIGHT. DO NOT STORE NEAR ORGANIC SUBSTANCES. PRODUCT IS HIGHLY HYGROSCOPIC. KEEP TIGHTLY CLOSED. Other Precautions:EMPTY CONTAINER MAY CONTAIN HAZARDOUS RESIDUES. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. WASH WELL AFTER USE. IN ACCORDANCE WITH GOOD STORAGE AND HANDLING PRACTICES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION IS INADEQUATE TO MAINTAIN VAPOR/DUST BELOW TLV WEAR NIOSH/MSHA APPROVED CHEMICAL CARTRIDGE RESPIRATOR. Ventilation:USE ADEQUATE VENTILATION. Protective Gloves:NEOPRENE OR POLYETHYLENE GLOVES. Eye Protection:CHEM WRKRS GOGG & FULL LGTH FSHLD Other Protective Equipment:MAKE EYE BATH AND EMERGENCY SHOWER AVAILABLE. APRON OR CLOTHING TO PROTECT SKIN. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: STRONGLY ACIDIC. MATLS TO AVOID: METAL, WATER, STRONG REDUCING AGENTS, STRONG BASES, CARBONATES, SULFIDES, CYANIDES, STRONG OXIDIZERS. ================== Physical/Chemical Properties ================== HCC:C1 pH:SUPDAT Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS TO LIGHT YELLOW ODORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ORG MATLS,CARBIDES, CHLORATES, FULMINATES, NITRATES, PICRATES, POWDERED METALS & OTHER COMBUST. ATTACKS MANY (SUPDAT) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HYDROGEN IS GENERATED BY ACTION OF ACID ON MOST METALS. SULFUR OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORD TO ALL APPLIC REGS. CAUTIOUSLY ADD TO LRG STIRRED EXCESS OF WATER. ADJUST PH TO NEUT, SEPARATE ANY INSOLUBLE SOLIDS/LIQS AND PACKAGE FOR HAZ WASTE DISP. FLUSH AQUEOUS SOLN DOWN DRAIN W/PLENTY O F H*2O. DISP OF I/A/W FED, ST & LOC REGS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.